Publications

2021-2025

107. P. K. Majhi, M. Zimmer, B. Morgenstern, V. Huch, D. Scheschkewitz* “Transition Metal Complexes of Heavier Vinylidenes: Allylic Coordination vs Vinylidene–Alkyne Rearrangement at Nickel”, J. Am. Chem. Soc.  2021, 143, 13350−13357. DOI: 10.1021/jacs.1c06453

106. Y. Heider, D. Scheschkewitz* “Molecular Silicon Clusters”, Chem. Rev.  2021, 121, 9674−9718. DOI: 10.1021/acs.chemrev.1c00052

105. A. T. Kell, N. M. Obeid, P. Bag, M. Zimmer, V. Huch, D. Scheschkewitz* “Reactivity of Phenylacetylene toward Unsymmetrical Disilenes: Regiodivergent [2+2] Cycloaddition vs. CH Addition”, Z. Anorg. Allg. Chem.  2021, 647, 1751−1758. DOI: 10.1002/zaac.202100137

104. P. K. Majhi, M. Zimmer, B. Morgenstern, D. Scheschkewitz* “Transition-Metal Complexes of Heavier Cyclopropenes: Non-Dewar–Chatt–Duncanson Coordination and Facile Si═Ge Functionalization”, J. Am. Chem. Soc.  2021, 143, 8981−8986. DOI: 10.1021/jacs.1c04419
Featured in Nature Reviews Chemistry: DOI: 10.1038/s41570-021-00307-z

103. T. Büttner, K. Weisshaar, P. Willmes, V. Huch, B. Morgenstern, R. Hempelmann,* D. Scheschkewitz* “Synthesis and electrochemistry of remotely thioether-functionalized disilenes”, Z. Anorg. Allg. Chem.  2021, 647, 1674−1678 (special issue on occasion of the 80th birthday of Prof. H. Schnöckel). DOI: 10.1002/zaac.202100161

102. L. Klemmer, A.-L. Thömmes, M. Zimmer, V. Huch, B. Morgenstern, D. Scheschkewitz,* “Metathesis of Ge=Ge double bonds”, Nat. Chem.  2021, 13, 373−377. DOI: 10.1038/s41557-021-00639-9

101. D. Dhara, D. Scheschkewitz,* V. Chandrasekhar,* C. B. Yildiz,* A. Jana* “Reactivity of NHC/diphosphene Au(I) hydride”, Chem. Commun.  2021, 57, 809−812. DOI: 10.1039/d0cc05461e

100. P. K. Majhi, V. Huch, D. Scheschkewitz,* “A Mixed Heavier Si=Ge Analogue of a Vinyl Anion”, Angew. Chem. Int. Ed.  2021, 60, 242−246. https://doi.org/10.1002/anie.202009406

 

2016-2020
 

99. K. I. Leszczyńska,* P. Deglmann, C. Präsang, V. Huch, M. Zimmer, D. Schweinfurth, D. Scheschkewitz, “Pentamethylcyclopentadienyl-substituted hypersilylsilylene: reversible and irreversible activation of C=C double bonds and dihydrogen”, Dalton Trans.  2020, 49, 13218−13225. https://doi.org/10.1039/D0CC04922K

98. N. E. Poitiers, V. Huch, M. Zimmer, D. Scheschkewitz,* “Chalcogen-Expanded unsaturated Silicon Clusters: Thia-, Selena-, and Tellurasiliconoids”, Chem. Eur. J.  2020, 26, 16599−116602. https://doi.org/10.1002/chem.202003180

97. N. E. Poitiers, V. Huch, M. Zimmer, D. Scheschkewitz,* “Nickel-assisted complete cleavage of CO by asilylene/siliconoid hybrid under formation of anSi=C enol ether bridge”, Chem. Commun.  2020, 56, 10898−10901. https://doi.org/10.1039/D0CC04922K

96. K. Samedov, Y. Heider, Y. Cai,* P. Willmes, D. Mühlhausen V. Huch, R. West, D. Scheschkewitz,* P. W. Percival,* “Free Radical chemistry of Phosphasilenes”, Angew. Chem. Int. Ed.  2020, 59, 16007−16012. http://doi.org/10.1002/anie.202006289

95. C. B. Yildiz, K. I. Leszczynska, S. González-Gallardo, M. Zimmer, A. Azizoglu, T. Biskup, C. W. M. Kay, V. Huch, H. S. Rzepa, D. Scheschkewitz,* “Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutanediyl”, Angew. Chem. Int. Ed. 2020, 59, 15087−15092. https://doi.org/10.1002/anie.202006283

94. N. E. Poitiers, L. Giarrana, V. Huch, M. Zimmer, D. Scheschkewitz,* “Exohedral functionalization vs. core expansion of siliconoids with Group 9 metals: catalytic activity in alkene isomerization”, Chem. Sci.  2020, 11, 7782−7788. https://doi.org/10.1039/d0sc02861d

93. Y. Kaiser, A. Grandjean, V. Huch, M. Zimmer, G. Jung, D. Scheschkewitz,* “Luminiscent Symmetrically and Unsymmetrically-Substituted Diboranes(4)”, Z. Anorg. All. Chem.  2020, 646, 816−827. https://doi.org/10.1002/zaac.202000032

92. N. Poitiers, L. Giarrana, K. I. Leszczynska, V. Huch, M. Zimmer, D. Scheschkewitz,* “Indirect and direct grafting of transition metals to siliconoids”, Angew. Chem. Int. Ed.  2020, 59, 8532−8536. http://dx.doi.org/oi.org/10.1002/anie.202001178

91. D. Dhara, S. Das, P. Kalita, S. K. Pati, D. Scheschkewitz,* V. Chandrasekhar,* A. Jana,* “Influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene”, Dalton Trans.  2020, 49, 993−997. http://dx.doi.org/10.1039/c9dt04690a

90. Y. Heider, P. Willmes, V. Huch, M. Zimmer, D. Scheschkewitz,* “Boron and phosphorus containing heterosiliconoids: stable p- and n-doped unsaturated silicon clusters”, J. Am. Chem. Soc.  2019, 141, 19498−19504. http://dx.doi.org/10.1021/jacs.9b11181

89. L. Klemmer, Y. Kaiser, V. Huch, M. Zimmer, D. Scheschkewitz,* “Persistent digermenes with Acyl and a-Chlorosilyl Functionalities”, Chem. Eur. J.  2019, 25, 12187−12195. http://dx.doi.org/10.1002/chem.201902553

88. D. Dhara, S. Das, S. K. Pati, D. Scheschkewitz,* V. Chandrasekhar,* A. Jana,* “NHC-coordinated diphosphene-stabilized gold(I) hydride and its reversible conversion to gold(I) formate with CO2, Angew. Chem. Int. Ed.  2019, 58, 15367−15371. http://dx.doi.org/10.1002/anie.201909798

87. L. Klemmer, V. Huch, A. Jana, D. Scheschkewitz,* “An anionic heterosiliconoid with two germanium vertices”, Chem. Comm.  2019, 55, 10100−10103. http://dx.doi.org/10.1039/c9cc04576g

86. B. Santra, R. S. Narayanan, P. Kalita, V. Kumar, D. Mandal, V. Gupta, M. Zimmer, V. Huch, V. Chandrasekhar,* D. Scheschkewitz,* C. Schulzke,* A. Jana*, “modulation of the nuclearity of molecular Mg(II)-phosphates: solid state structural change involving coordinating solvent”, Dalton Trans.  2019, 48, 8853−8860. http://dx.doi.org/10.1039/c9dt00687g

85. Y. Heider, N. Poitiers, P. Willmes, K. Leszczynska, V. Huch, D. Scheschkewitz,* “Site-Selective Functionalization of Si6R6 Siliconoids”, Chem. Sci.   2019, 10, 4523−4530. http://dx.doi.org/10.1039/c8sc05591b

84. A. T. Henry, J. L. Bourque, I. Vacirca, D. Scheschkewitz, K. M. Baines,* “The Addition of a Cyclopropyl Alkyne to an Asymmetrically-Substituted Disilene: A Mechanistic Study”, Organometallics   2019, 38, 1622−1626. http://dx.doi.org/10.1021/acs.organomet.9b00054

83. K. I. Leszczynska,* V. Huch, C. Präsang, J. Schwabedissen, R. Berger,* D. Scheschkewitz,* “Atomically Precise Expansion of Unsaturated Silicon Clusters”, Angew. Chem. Int. Ed.   2019, 58, 5124−5128. https://doi.org/10.1002/anie.201811331

82. A. Maiti, D. Mandal, I. Omlor, D. Dhara, L. Klemmer, V. Huch, M. Zimmer, D. Scheschkewitz,* A. Jana,* “Equilibrium Coordination of NHCs to Si(IV) Species and Donor Exchange in Donor−Acceptor Stabilized Si(II) and Ge(II) Compounds”, Inorg. Chem.  2019, 58, 4071−4075. https://doi.org/10.1021/acs.inorgchem.9b00246

81. Y. Heider, P. Willmes, D. Mühlhausen, L. Klemmer, M. Zimmer, V. Huch, D. Scheschkewitz,* “A Three‐Membered Cyclic Phosphasilene”, Angew. Chem. Int. Ed.  2019, 58, 1939−1944. https://doi.org/10.1002/anie.201811944

80. F. Philippi, D. Rauber, J. Zapp, C. Präsang, D. Scheschkewitz, R. Hempelmann,* “Multiple Ether‐Functionalized Phosphonium Ionic Liquids as Highly Fluid Electrolytes”, ChemPhysChem  2019, 20, 443−455. doi.org/10.1002/cphc.201800939

79. A. Stahlich, V. Huch, A. Grandjean, K. Rohe, K. Leszczyńska, D. Scheschkewitz, A. Schäfer,* „Permethylated Disila[2]metallocenophanes of Group 14 and 15 Elements”, Chem. Eur. J.  2019, 25, 173−176. https://doi.org/10.1002/chem.201804934

78. B. Santra, D. Mandal, V. Gupta, P. Kalita, V. Kumar, R. S. Narayanan, A. Dey, N. Chrysochos, A. Mohammad, A. Singh, M. Zimmer, R. Dalapati, S. Biswas,* C. Schulzke,* V. Chandrasekhar,* D. Scheschkewitz,* A. Jana,* “Structural Diversity in Supramolecular Organization of Anionic Phosphate Monoesters: Role of Cations”, ACS Omega  2019, 4, 2118−2133. https://doi.org/10.1021/acsomega.8b03192

77. H. Zhao, L. Klemmer, M. J. Cowley, V. Huch, M. Zimmer, D. Scheschkewitz,* “Reactivity of a Peraryl Cyclotrisilene (c-Si3R4) Toward Chalcogens”, Z. Anorg. Allg. Chem. 2018, 644, 999−1005. doi.org/10.1002/zaac.201800182

76. H. Zhao, L. Klemmer, M. J. Cowley, M. Majumdar, V. Huch, M. Zimmer, D. Scheschkewitz,* “Phenylene-Bridged Cross-Conjugated 1,2,3-Trisilacyclopentadienes”, Chem. Commun.  2018, 54, 8399−8402. https://doi.org/10.1039/C8CC03297

75. A.-C. Andres, J. Beckmann, L. Klemmer, S. Muth, D. Scheschkewitz,* M. Springborg,* “Structure and Stability of Propellane-Like E2E'2E''2H6, J. Mol. Mod.  2018, 24, 190. https://doi.org/10.1007/s00894-018-3713-9

74. Y. Heider, D. Scheschkewitz,* “Stable Unsaturated Silicon Clusters (Siliconoids)”, Dalton Trans.  2018, 47, 7104–7112. https://doi.org/10.1039/C8DT01009A

73. D. Dhara, P. Kalita, S. Mondal, R. S. Narayanan, K. R. Mote, V. Huch, M. Zimmer, C. B. Yildiz,* D. Scheschkewitz,* V. Chandrasekhar,* A. Jana,* “Reactivity Enhancement of a Diphosphene by Reversible N-Heterocyclic Carbene Coordination”, Chem. Sci.  2018, 9, 4235–4243. http://dx.doi.org/10.1039/c8sc00348c

72. D. Nieder, L. Klemmer, Y. Kaiser, V. Huch, D. Scheschkewitz,* “Isolation and Reactivity of a Digerma Analogue of Vinyllithiums: a Lithium Digermenide”, Organometallics  2018, 37, 632–635. https://doi.org/10.1021/acs.organomet.7b00470

71. D. Dhara, V. Huch, D. Scheschkewitz,* A. Jana,* „Synthesis of a a-Chlorosilyl Functionalized Donor-Stabilized Chlorogermylene”, Inorganics  2018, 6, 6. http://dx.doi.org/10.3390/inorganics6010006

70. H. Zhao, K. Leszczyńska, L. Klemmer, V. Huch, M. Zimmer, D. Scheschkewitz,* "Disilenyl Silylene-Like Reactivity of a Cyclotrisilene", Angew. Chem. Int. Ed.  2018, 57, 2445–2449. http://dx.doi.org/10.1002/anie.201711833

69. D. Mandal, D. Dhara, A. Maiti, L. Klemmer, V. Huch, M. Zimmer, H. S. Rzepa,* D. Scheschkewitz,* A. Jana,* "Mono- and Dicoordinate Germanium(0) as Four Electron Donor", Chem. Eur. J.  2018, 24, 2873–2878. http://dx.doi.org/10.1002/chem.201800071

68. A. Rammo, D. Scheschkewitz,* "Functional Disilenes in Synthesis", Chem. Eur. J2018, 24, 6866–6885. http://dx.doi.org/10.1002/chem.201704090

67. C. B. Yildiz,* D. Scheschkewitz,* "Reactivity of Heavier Vinyl Anions [(CH3)(2)E=E '(CH3)]− (E, E' = C, Si, Ge) toward Carbon Monoxide: A Computational Study", Organometallics  2017, 36, 3035–3042. http://dx.doi.org/10.1021/acs.organomet.7b00327

66. N. M. Obeid, L. Klemmer, D. Maus, M. Zimmer, J. Jeck, I. Bejan, A. J. P. White, V. Huch, G. Jung,* D. Scheschkewitz,* "(Oligo)Aromatic Species with one or two Conjugated Si=Si Bonds: Near-IR Emission of Anthracenyl-Bridged Tetrasiladiene", Dalton Trans.  2017, 46, 8839–8848. http://dx.doi.org/10.1039/C7DT00397H

65. N. Zapp, K. Rohe, R. Ye, D. Scheschkewitz, M. Springborg,* "Spherical Aromaticity in C-, Si-, and Ge-Containing Compounds", Comp. Theor. Chem.  2017, 1102, 5–14. http://dx.doi.org/10.1016/j.comptc.2016.12.040

64. D. Nieder, V. Huch, C. B. Yildiz, D. Scheschkewitz,* "Regiodiscriminating Reactivity of Isolable NHC-Coordinated Disilenyl Germylene and Its Cyclic Isomer", J. Am. Chem. Soc.  2016, 138, 13996–14005. http://dx.doi.org/10.1021/jacs.6b07815  

63. P. Willmes, L. Junk, V. Huch, C. B. Yildiz, D. Scheschkewitz,* "Diverse Reactivity of an Electrophilic Phosphasilene towards Anionic Nucleophiles: Substitution or Metal–Amino Exchange", Angew. Chem. Int. Ed.  2016, 55, 10913–10917. http://dx.doi.org/10.1002/anie.201605699

62. D. Nieder, C. B. Yildiz, A. Jana , M. Zimmer, V, Huch, D. Scheschkewitz,* "Dimerization of a Marginally Stable Disilenyl Germylene to Tricyclic Systems: Evidence for Reversible NHC-Coordination", Chem. Commun.  2016, 52, 2799–2802. http://dx.doi.org/10.1039/C5CC09878E

61. P. Willmes, K. Leszczyńska, Y. Heider, K. Abersfelder, M. Zimmer, V. Huch, D. Scheschkewitz,* "Isolation and Versatile Derivatization of an Unsaturated Anionic Silicon Cluster (Siliconoid)", Angew. Chem. Int. Ed.  2016, 55, 2907–2910. http://dx.doi.org/10.1002/anie.201511037

60. C. Präsang, D. Scheschkewitz,* "Reactivity in the Periphery of Functionalised Multiple Bonds of Heavier Group 14 Elements", Chem. Soc. Rev.  2016, 45, 900–921. http://dx.doi.org/10.1039/c5cs00720h

2011-2015
 

59. K. Abersfelder, H. Zhao, A. J. P. White, C. Präsang, D. Scheschkewitz,* "Synthesis of the First Homoleptic Trisilaallyl Chloride: ­3-Chloro-1, 1,2, 3,3-pentakis(2′,4′,6′-triisopropylphenyl)trisil-1-ene", Z. Anorg. Allg. Chem.  2015, 641, 2051–2055 (Sonderband anläßlich des 60. Geburtstags von Prof. F. E. Hahn). http://dx.doi.org/10.1002/zaac.201500561

58. M. Majumdar, I. Omlor, C. B. Yildiz, A. Azizoglu, V. Huch, D. Scheschkewitz,* "Reductive Cleavage of Carbon Monoxide by a Disilenide", Angew. Chem. Int. Ed.  2015, 54, 8746–8750. http://dx.doi.org/10.1002/anie.201503455 (Hot Paper)

57. A. Jana, V. Huch, H. S. Rzepa, D. Scheschkewitz,* "A Molecular Complex with a Formally Neutral Iron Germanide Motif (Fe2Ge2)", Organometallics  2015, 34, 2130–2133. http://dx.doi.org/10.1021/om501286g

56. T. P. Robinson, M. J. Cowley, D. Scheschkewitz,* J. M. Goicoechea,* "Phosphide Delivery to a Cyclotrisilene", Angew. Chemie  2015,127, 693–696; Angew. Chem. Int. Ed.  2015, 54, 683–686. http://dx.doi.org/10.1002/anie.201409908

55. A. Jana, V. Huch, H. S. Rzepa, D. Scheschkewitz, "A Multiply Functionalized Base-Coordinated Ge-II Compound and Its Reversible Dimerization to the Digermene", Angew. Chem. Int. Ed.  2015, 54, 289–292. http://dx.doi.org/10.1002/anie.201407751 (VIP)

54. A. Jana, I. Omlor, V. Huch, H. S. Rzepa, D. Scheschkewitz, "N-Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes", Angew. Chem. Int. Ed.  2014, 53, 9953–9956. http://dx.doi.org/10.1002/anie.201405238

53. M. J. Cowley, V. Huch, D. Scheschkewitz,* "Donor-Acceptor Adducts of a 1,3-Disila-2-oxyallyl Zwitterion", Chem. Eur. J.  2014, 20, 9221–9224. http://dx.doi.org/10.1002/chem.201402750

52. M. Majumdar, I. Bejan, V. Huch, A. J. P. White, G. R. Whittell, A. Schäfer, I. Manners,* D. Scheschkewitz,* "s-p Conjugated Organosilicon Hybrid Polymers from Copolymerization of a Tetrasiladiene and 1,4-Diethynylbenzene", Chem. Eur. J.  2014, 20, 9225–9229. http://dx.doi.org/10.1002/chem.201403494

51. A. Jana, V. Huch, M. Repisky, R. J. F. Berger,* D. Scheschkewitz,* "Dismutational and Global-Minimum Isomers of Heavier 1,4-Dimetallatetrasilabenzenes of Group 14", Angew. Chem. Int. Ed.  2014, 53, 3513–3518. http://dx.doi.org/10.1002/anie.201310475

50. A. Jana, M. Majumdar, V. Huch, M. Zimmer, D. Scheschkewitz,* "NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand", Dalton Trans. 2014, 43, 5175–5181.http://dx.doi.org/10.1039/C4DT00094C

49. P. Willmes, M. J. Cowley, M. Hartmann, M. Zimmer, V. Huch, D. Scheschkewitz,* "From Disilene (Si=Si) to Phosphasilene (Si=P) and Phosphacumulene (P=C=N)", Angew. Chem. Int. Ed. 2014, 53, 2216–2220. http://dx.doi.org/10.1002/anie.201308525

48. M. J. Cowley, Y. Ohmori, V. Huch, M. Ichinohe, A. Sekiguchi,* D. Scheschkewitz,* "Carbonylation of Cyclotrisilenes", Angew. Chem. Int. Ed. 2013, 52, 13247–13250. http://dx.doi.org/ 10.1002/anie.201307450 (VIP)

47. A. Jana, V. Huch, D. Scheschkewitz* „NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene“,Angew. Chem. Int. Ed. 2013, 52, 12179–12182. http://dx.doi.org/10.1002/anie.201306780 (VIP)

46. M. J. Cowley, V. Huch, H. S. Rzepa, D. Scheschkewitz,* „Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene“, Nature Chem. 2013, 5, 876–879. http://dx.doi.org/10.1038/nchem.1751

45. A. Meltzer, M. Majumdar, A. J. P. White, V. Huch, D. Scheschkewitz,* „Potential Protecting Group Strategy for Disila Analogues of Vinyllithiums: Synthesis and Reactivity of a 2,4,6-Trimethoxyphenyl-Substituted Disilene“, Organometallics 2013, 22,6844–6850. http://dx.doi.org/10.1021/om400545w

44. A. Rammo, I. Bejan, A. Meltzer, K. Radacki, H. Braunschweig, D. Scheschkewitz,* „1,2-Disilabicyclo[1.1.1]pentan-4-ones from a Disilenide and Acryloyl Chlorides“, Aust. J. Chem. 2013, 66, 1311–1314. http://dx.doi.org/10.1071/CH13265 

43. D. Kratzert, D. Leusser, J. J. Holstein, B. Dittrich, K. Abersfelder, D. Scheschkewitz, D. Stalke, „An Experimental Charge Density Study of Two Isomers of Hexasilabenzene“, Angew. Chem. Int. Ed. 2013, 52, 4478–4482. http://dx.doi.org/10.1002/anie.201209906

42. Y. Ohmori, M. Ichinohe, A. Sekiguchi,* M. J. Cowley, V. Huch, D. Scheschkewitz,* „Functionalized Cyclic Disilenes via Ring Expansion of Cyclotrisilenes with Isocyanides“, Organometallics 2013, 32, 1591–1594. http://dx.doi.org/10.1021/om400054u

41. M. Majumdar, V. Huch, I. Bejan, A. Meltzer, D. Scheschkewitz, „Reversible, Complete Cleavage of Si=Si Double Bonds by Isocyanide Insertion “,Angew. Chem. Int. Ed. 2013, 52, 3516–3520. http://dx.doi.org/10.1002/anie.201209281

40. D. Scheschkewitz*, „The Disilyne Chameleon - Blue,  Yellow and/or Green?“, Z. Anorg. Allg. Chem. 2012, 638, 2381–2383 (eingeladene Zuschrift). http://dx.doi.org/10.1002/zaac.201210017

39. K. Abersfelder, A. Russell, H. S. Rzepa, A. J. P. White, P. R. Haycock, D. Scheschkewitz*, „Contraction and Expansion of the Silicon Scaffold of Stable Si6R6 Isomers “, J. Am. Chem. Soc. 2012, 134, 16008–16016. http://dx.doi.org/10.1021/ja307344f

38. K. Leszczyńska, K. Abersfelder, M. Majumdar, B. Neumann, H.-G. Stammler, H. S. Rzepa, P. Jutzi*, D. Scheschkewitz*, „The Cp*Si+ Cation as a Stoichiometric Source of Silicon“, Chem. Commun. 2012, 48, 7820–7822.http://dx.doi.org/10.1039/C2CC33911K

37. K. Leszczyńska, K. Abersfelder, A. Mix, B. Neumann, H.-G. Stammler, M. J. Cowley, P. Jutzi*, D. Scheschkewitz*, Reversible Base Coordination to a Disilene“, Angew. Chem. Int. Ed. 2012, 51, 6785–6788. http://dx.doi.org/10.1002/anie.201202277  

36. M. J. Cowley, K. Abersfelder, A. J. P. White, M. Majumdar, D. Scheschkewitz*, ” Transmetallation Reactions of a Lithium Disilenide“, Chem. Commun. 2012, 48, 6595–6597. http://dx.doi.org/10.1039/C2CC33047D

35. K. Abersfelder, A. J. P. White, R. J. F. Berger, H. S. Rzepa, D. Scheschkewitz*, „ A Stable Derivative of the Global Minimum on the Si6H6 Potential Energy Surface “, Angew. Chem. Int. Ed.  2011, 50, 7936–7939 (Hot Paper). http://dx.doi.org/10.1002/anie.201102623

34. D. Scheschkewitz*,”Reversible Formation of a Blue Arsasilene and Isolation of Air-Stable Emissive Disilenes“, Angew. Chem. Int. Ed. 2011, 50, 3118–3119 (Übersicht).
http://dx.doi.org/10.1002/anie.201007688

33. D. Scheschkewitz*, „The Versatile Chemistry of Disilenides: Disila Analogues of Vinyl Anions as Synthons in Low-valent Silicon Chemistry“, Chem. Lett.  2011, 40, 2–11 (eingeladene Übersicht).
http://dx.doi.org/10.1246/cl.2011.2

2006-2010
 

32. R. J. F. Berger*, H. S. Rzepa, D. Scheschkewitz, „Ring Currents in the Dismutational Aromatic Si6R6“, Angew. Chem. Int. Ed.  2010, 49, 10006–10009.  http://dx.doi.org/10.1002/anie.201003988

31. J. Jeck, I. Bejan, A. J. P. White, D. Nied, F. Breher*, D. Scheschkewitz*, „Transfer of a Disilenyl Moiety to Aromatic Substrates and Lateral Functional Group Transformation in Aryl Disilenes“, J. Am. Chem. Soc. 2010, 132, 17306–17315. http://dx.doi.org/10.1021/ja107547s

30. D. Scheschkewitz*, „Comment on Single-Crystal X-ray Structure of 1,3-Dimethylcyclobutadiene by Confinement in a Crystalline Matrix“, Science 2010, 330, 1047–1048. http://dx.doi.org/10.1126/science.1195752
Featured in C&E News: http://pubs.acs.org/isubscribe/journals/cen/88/i47/html/8847scic2.html

29. M. Hartmann, A. Haji-Abdi, K. Abersfelder, P. R. Haycock, A. J. P. White, D. Scheschkewitz*, „Synthesis, Characterisation and Complexation of Phosphino Disilenes“, Dalton Trans. 2010, 39, 9288–9295 (eingeladene Zuschrift). http://dx.doi.org/10.1039/c0dt00180e

28. K. Abersfelder, D. Scheschkewitz*, „Synthesis of Homo- and Heterocyclic Silanes via Intermediates with Si=Si bonds“, Pure Appl. Chem. 2010, 82, 595–602. (eingeladene Zuschrift). http://dx.doi.org/10.1351/PAC-CON-09-08-09

27. K. Abersfelder, Andrew J. P. White, Henry S. Rzepa,* D. Scheschkewitz*, „A Tricyclic Aromatic Isomer of Hexasilabenzene“, Science 2010, 327, 564–566. http://dx.doi.org/10.1126/science.1181771
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and Chemistry World:
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26. T. Zweifel, D. Scheschkewitz, T. Ott, M. Vogt, H. Grützmacher*, „Chiral [Bis(olefin)amine]rhodium(I) Complexes - Transfer Hydrogenation in Ethanol“, Eur. J. Inorg. Chem. 2009, 5561–5576. http://dx.doi.org/10.1002/ejic.200900875

25. K. Abersfelder, T.-l. Nguyen, D. Scheschkewitz*, „Stannyl-Substituted Disilenes and a Disilastannirane“, Z. Anorg. Allg. Chem. 2009, 635, 2093–2098 (eingeladene Zuschrift). http://dx.doi.org/10.1002/zaac.200900234

24. D. Scheschkewitz*, „Anionic Reagents with Silicon Containing Double Bonds“, Chem. Eur. J. 2009, 15, 2476–2485. http://dx.doi.org/10.1002/chem.200801968

23. I. Bejan, S. Inoue, M. Ichinohe, A. Sekiguchi*, D. Scheschkewitz*, „1,2Disilacyclobut2enes: Donorfree Four-Membered Cyclic Silenes from Reaction of Disilenides with Vinylbromides“, Chem. Eur. J. 2008, 14, 7119–7122. http://dx.doi.org/10.1002/chem.200800919

22. K. Abersfelder, D. Scheschkewitz*, „ Syntheses of Trisila Analogues of Allyl Chlorides and their Transformations to Chloro Cyclotrisilanes, Cyclotrisilanides and a Trisilaindane “, J. Am. Chem. Soc.  2008, 130, 4114–4121. http://dx.doi.org/10.1021/ja711169w

21. D. Scheschkewitz, „A Base-Stabilized Neutral B-B Bond: Closing a Gap by Filling the Void“, Angew. Chem. Int. Ed. 2008, 47, 1995–1997 (Review). http://dx.doi.org/10.1002/anie.200705459

20. I. Bejan, D. Scheschkewitz*, „Two Si-Si double bonds connected by a phenylene bridge“, Angew. Chem. Int. Ed. 2007, 46, 5783–5786 (VIP). http://dx.doi.org/10.1002/anie.200701744

19. J.-B. Bourg, A. Rodriguez, D. Scheschkewitz, H. Gornitzka, D. Bourissou*, G. Bertrand*, „Thermal Valence Isomerization of Heterobutadienes (PBBP) to Bicyclo[1.1.0]butanes and Cyclobutane-1,3-diyls: Analogies and Differences with Butadiene Analogues“, Angew. Chem. Int. Ed. 2007, 46, 5741–5745. http://dx.doi.org/10.1002/anie.200701578

18. I. Bejan, D. Güclü, S. Inoue, M. Ichinohe, A. Sekiguchi, D. Scheschkewitz*, „Stable Cyclic Silenes from Reaction of Disilenides with Carboxylic Acid Chlorides“, Angew. Chem. Int. Ed.  2007, 46, 3349–3352.  http://dx.doi.org/10.1002/anie.200700067

17. C. Präsang, P. Amseis, D. Scheschkewitz, G. Geiseler, W. Massa, M. Hofmann, A. Berndt*, „Strong Neutral Homoaromatics“, Angew. Chem. Int. Ed. 2006, 45, 6745–6747. http://dx.doi.org/10.1002/anie.200602073

16. K. Abersfelder, D. Güclü, D. Scheschkewitz*, „An Unsaturated a,w-Dianionic Oligosilane“, Angew. Chem. Int. Ed. 2006, 45, 1643–1645. http://dx.doi.org/10.1002/anie.200503975

1999-2005
 

15. D. Scheschkewitz, P. Amseis, G. Geiseler, W. Massa, M. Hofmann, A. Berndt*, „Classical 1,2,4-Triboracyclopentanes and Their Rearrangement into Nonclassical 2-Boryl-1,3-diboracyclobutanes: Intramolecular C-H Bond Activation by a B-B Moiety“, Eur. J. Inorg. Chem.  2005, 4078–4085. http://dx.doi.org/10.1002/ejic.200500279

14. H. Braunschweig*, K. Radacki, D. Rais, D. Scheschkewitz, „A T-Shaped Platinum(II) Boryl Complex as the Precursor to a Platinum Compound with a Base-Stabilized Borylene Ligand“, Angew. Chem. Int. Ed. 2005, 44, 5651–5654 (Cover Picture, VIP). http://dx.doi.org/10.1002/anie.200501588

13. T. Nguyen, D. Scheschkewitz*, „Activation of a Si=Si Bond by η1-Coordination to a Transition Metal“, J. Am. Chem. Soc. 2005, 127, 10174–10175.  http://dx.doi.org/10.1021/ja052593p

12. D. Scheschkewitz*, „A Molecular Silicon Cluster with a “Naked” Vertex Atom“, Angew. Chem. Int. Ed. 2005, 44, 2954–2956. http://dx.doi.org/10.1002/anie.200462730

11. H. Braunschweig*, K. Radacki, D. Scheschkewitz, G. Whittell, „Boron as a Bridging Ligand“, Angew. Chem. Int. Ed.  2005, 44, 1658–1660 (VIP). http://dx.doi.org/10.1002/anie.200463026

10. A. Rodriguez, R. A. Olsen, N. Ghaderi, D. Scheschkewitz, F. S. Tham, L. J. Mueller, G. Bertrand*; „Evidence for the Coexistence of Two Bond-Stretch Isomers in Solution“,Angew. Chem. Int. Ed. 2004, 43, 4880–4883. http://dx.doi.org/10.1002/anie.200460475

9. D. Scheschkewitz*; „A Silicon Analogue of Vinyllithium: Structural Characterization of a Disilenide“, Angew. Chem. Int. Ed. 2004, 43, 2965–2967. http://dx.doi.org/10.1002/anie.200353347
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8. D. Scheschkewitz, H. Amii, W. W. Schoeller, D. Bourissou, G. Bertrand*; „s-Bond Stretching: a Static Approach for a Dynamic Process“, Angew. Chem. Int. Ed. 2004, 43, 585–587 (Cover Picture). http://dx.doi.org/10.1002/anie.200352944

7. M. Otto, D. Scheschkewitz, T. Kato, M. M. Midland, J. B. Lambert, G. Bertrand*; „The Stable Pentamethylcyclopentadiene Cation Remains Unknown“, Angew. Chem. Int. Ed. 2002, 41, 2275–2276. http://dx.doi.org/10.1002/1521-3773(20020703)41:13<2275::AID-ANIE2275>3.0.CO;2-1

6. D. Scheschkewitz, H. Amii, H. Gornitzka, W. W. Schoeller, D. Bourissou, G. Bertrand*; „Singlet Diradicals: From Transition States to Crystalline Compounds“, Science 2002, 295, 1880–1881. http://dx.doi.org/10.1126/science.1068167

5. D. Scheschkewitz, M. Hofmann, A. Ghaffari, P. Amseis, C. Präsang, W. Mesbah, G. Geiseler, W. Massa, A. Berndt*; „Very Strong Anionic Homoaromaticity in (deloc-1,3,4)-1-Sila-3,4-Diboracyclopentane-1-ides, the Importance of the Energy of the Reference System for Homoaromatic Stabilization Energies“, J. Organomet. Chem.  2002, 646, 262–270. http://dx.doi.org/10.1016/S0022-328X(01)01435-8

4. D. Scheschkewitz, A. Ghaffari, P. Amseis, M. Unverzagt, G. Subramanian, M. Hofmann, P. v. R. Schleyer , H. F. Schäfer III, G. Geiseler, W. Massa, A. Berndt*; „Bishomoaromatic 1,2,4-Triboracyclopentane Dianions: Strong Three-Center, Two-Electron Bonds between Three Boron Atoms“, Angew. Chem. Int. Ed.  2000, 39, 1272–1275.http://dx.doi.org/10.1002/(SICI)1521-3773(20000403)39:7<1272::AID-ANIE1272>3.0.CO;2-Z

3. M. Hofmann, D. Scheschkewitz, A. Ghaffari, G. Geiseler, W. Massa, H. F. Schaefer III, A. Berndt*; „Two-Electron Aromatics with Classical and Non-Classical Homobridges“, J. Mol. Model. 2000, 6, 257–271.http://dx.doi.org/10.1007/s0089400060257

2. M. Stürmann, W. Saak, M. Weidenbruch*, A. Berndt, D. Scheschkewitz; „Molecular Structures of New Compounds with Ge/C and Sn/C Double Bonds“, Heteroatom Chem. 1999, 10, 554–558.http://dx.doi.org/10.1002/(SICI)1098-1071(1999)10:7<554::AID-HC7>3.0.CO;2-X

1. D. Scheschkewitz, M. Menzel, M. Hofmann, P. v. R. Schleyer, G. Geiseler, W. Massa, K. Harms, A. Berndt*; „A Five-Membered Ring with Three Negative Charges and Solvent-Free Lithium Counterions“, Angew. Chem. Int. Ed. 1999, 38, 2936–2939 (VIP). http://dx.doi.org/10.1002/(SICI)1521-3773(19991004)38:19<2936::AID-ANIE2936>3.0.CO;2-9

Patents
 

4. D. Schweinfurth, L. Mayr, D. Waldmann, S. Weiguny, D. Scheschkewitz, K. I. Leszczynska, „Process for the Generation of Thin Silicon-Containing Films,WO2018/202572Al, 08.11.2018.

3. M. Ahlf, K. Schierle-Arndt, D. Schweinfurth, T. Adermann, D. Loeffler, S. Weiguny, K. I. Leszczynska, D. Scheschkewitz, „Process for the Generation of Thin Silicon-Containing Films,WO2018/108628Al, 21.06. 2018.

2. M. Ahlf, D. Schweinfurth, L. Mayr, K. I. Leszczynska, D. Scheschkewitz, „Process for the Generation of Thin Silicon-Containing Films,WO2018/077684Al, 03.05.2018.

1. H. Grützmacher, T. Büttner, P. Maire, M. Ramseier, D. Scheschkewitz, T. Zweifel, „Tropylideneamines and Use Thereof“,US20060036109, CN1706805 (A); EP1614674; JP2006008682; DE102004027771.